Keywords in headings (<H1>, <H2>, etc. tags)One more place where keywords count a lot. But beware that your page has actual text about the particular keyword.
Keywords in the beginning of a document
Also counts, though not as much as anchor text, title tag or headings. However, have in mind that the beginning of a document does not necessarily mean the first line. It is advisable to seamlessly integrate the targeted keyword so that it appears towards the a) Top left b) bottom right of the document page and in the middle content paragraphs.